Zhong‐Ming Sun

Nankai University

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i-10 index

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Weiting Yang

Hainan University

151

Song Dang

Chinese Academy of Sciences

Qing‐Jiang Pan

Heilongjiang University

Lei‐Jiao Li

Changchun University of Science and Technology

Fei‐Yan Yi

Ningbo University

Alexander I. Boldyrev

Utah State University

John E. McGrady

University of Oxford

ÁM

Álvaro Muñoz-Castro

San Sebastián University

Jiang‐Gao Mao

Fujian Institute of Research on the Structure of Matter

Nikolay V. Tkachenko

Lawrence Berkeley National Laboratory

Cooperative Institutions

Chinese Academy of Sciences

153

University of Chinese Academy of Sciences

Changchun Institute of Applied Chemistry

Jilin University

University of Science and Technology of China

Nankai University

Fujian Institute of Research on the Structure of Matter

Peking University

Central South University

Harbin Institute of Technology

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CCDC 939428: Experimental Crystal Structure Determination

The Cambridge Structural Database (2014)

Junfeng Liu Fuxing Pan Shuang Yao Min Xue Dongmei Cui

An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures.

10.5517/cc10jk47

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CCDC 939429: Experimental Crystal Structure Determination

The Cambridge Structural Database (2014)

Junfeng Liu Fuxing Pan Shuang Yao Min Xue Dongmei Cui

10.5517/cc10jk58

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A cluster-based mesoporous Ti-MOF with sodalite supercages

Chemical Communications (2017)

Chao Wang Chao Liu Xiang He Zhong‐Ming Sun

The cooperative assembly of a hexagonal column shaped [Ti6O6][iPrO]66+ cluster and rhomboid Cu2I2 dimers using isonicotinic acid results in an unprecedented three-dimensional (3D) highly crystalline cluster-based Ti-MOF that features both giant sodalite cages with an inner diameter of 2.8 × 3.2 nm2 and 3D open square channels.

Sodalite

10.1039/c7cc06652j

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Citations (74)

Diversity of Functionalized Germanium Zintl Clusters: Syntheses and Theoretical Studies of [Ge9PdPPh3]3− and [Ni@(Ge9PdPPh3)]2−

Journal of Cluster Science (2009)

Zhong‐Ming Sun Ya‐Fan Zhao Jun Li Lai‐Sheng Wang

Bimetallic strip

Ethylene diamine

Nanochemistry

10.1007/s10876-009-0266-1

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Citations (36)

Se₂(B₂O₇): A New Type of Second‐Order NLO Material.

ChemInform (2006)

Fang Kong Shuping Huang Zhong‐Ming Sun Jiang‐Gao Mao Wen‐Dan Cheng

Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.

10.1002/chin.200638009

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Solvents control over the degree of interpenetration in metal-organic frameworks and their high sensitivities for detecting nitrobenzene at ppm level

Journal of Materials Chemistry (2012)

Min Guo Zhong‐Ming Sun

Solvothermal syntheses in DMF and acetonitrile afforded two novel MOFs, Zn3(L1)2(L2)·3.6 DMF·4.0 H2O (1) and Zn3(L1)2(L2) (2) [L1 = 4-[3-(4-carboxyphenoxy)-2-[(4-carboxyphenoxy)methyl]-2-methyl-propoxy]benzoate, L2 = 1,4-bis(1-imidazolyl)benzene], respectively. Single crystal X-ray analyses reveal that 1 and 2 are structurally closely related with the same building blocks and 3-dimesional 3, 8-connected tfz-d net. 1 is based on a 2-fold interpenetrating network with extra-framework DMF and water molecules located in the void space, while 2 is different in its 3-fold interpenetrating network and absence of any solvent molecules. This simple and easy strategy unprecedentedly controls the degree of interpenetration in MOFs through varying solvents. Luminescent properties of activated phase 1′ and 2 well dispersed in different solvents have also been investigated systematically, which demonstrate distinct solvent-dependent luminescent spectra with emission intensities significantly quenched toward nitrobenzene (NB). For luminescence responses of 1′ and 2 dispersed in DMF solution with gradually increased NB contents, detectable quenching effects were observed even at a very low NB concentration of 50 ppm, indicating extremely high sensitivities of 1′ and 2 towards NB.

Nitrobenzene

Biphenyl

10.1039/c2jm32066e

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Citations (174)

An all-metal fullerene: [K@Au ₁₂ Sb ₂₀ ] ⁵⁻

Science (2023)

Yu‐He Xu Wen‐Juan Tian Álvaro Muñoz-Castro Gernot Frenking Zhong‐Ming Sun

The C60 fullerene molecule has attracted tremendous interest for its distinctive nearly spherical structure. By contrast, all-metal counterparts have been elusive: Fullerene-like clusters composed of noncarbon elements typically suffer from instability, resulting in more compact geometries that require multiple embedded atoms or external ligands for stabilization. In this work, we present the synthesis of an all-metal fullerene cluster, [K@Au12Sb20]5-, using a wet-chemistry method. The cluster's structure was determined by single crystal x-ray diffraction, which revealed a fullerene framework consisting of 20 antimony atoms. Theoretical calculations further indicate that this distinct cluster exhibits aromatic behavior.

Fullerene chemistry

10.1126/science.adj6491

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Citations (17)

Peculiar All‐Metal σ‐Aromaticity of the [Au₂Sb₁₆]⁴⁻ Anion in the Solid State

Angewandte Chemie International Edition (2016)

Ivan A. Popov Fuxing Pan Xue‐Rui You Lei‐Jiao Li Eduard Matito

Abstract Gas‐phase clusters are deemed to be σ‐aromatic when they satisfy the 4 n +2 rule of aromaticity for delocalized σ electrons and fulfill other requirements known for aromatic systems. While the range of n values was shown to be quite broad when applied to short‐lived clusters found in molecular‐beam experiments, stability of all‐metal cluster‐like fragments isolated in condensed phase was previously shown to be mainly ascribed to two electrons ( n =0). In this work, the applicability of this concept is extended towards solid‐state compounds by demonstrating a unique example of a storable compound, which was isolated as a stable [K([2.2.2]crypt)] + salt, featuring a [Au 2 Sb 16 ] 4− cluster core possessing two all‐metal aromatic AuSb 4 fragments with six delocalized σ electrons each ( n =1). This discovery pushes the boundaries of the original idea of Kekulé and firmly establishes the usefulness of the σ‐aromaticity concept as a general idea for both small clusters and solid‐state compounds.

10.1002/anie.201609497

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Citations (51)

Methoxy-Directed Aryl-to-Aryl 1,3-Rhodium Migration

Journal of the American Chemical Society (2013)

Jing Zhang Junfeng Liu Angel Ugrinov Anthony F. X. Pillai Zhong‐Ming Sun

Through-space metal/hydrogen shift is an important strategy for transition-metal-catalyzed C-H bond activation. Here we describe the synthesis and characterization of a Rh(I) 2,6-dimethoxybenzoate complex that underwent stoichiometric rearrangement via a highly unusual 1,3-rhodium migration. This aryl-to-aryl 1,3-Rh/H shift was also demonstrated in a Rh(I)-catalyzed decarboxylative conjugate addition to form a C-C bond at a meta position instead of the ipso-carboxyl position. A deuterium-labeling study under the conditions of Rh(I)-catalyzed protodecarboxylation revealed the involvement of an ortho-methoxy group in a multistep pathway of consecutive sp(3) and sp(2) C-H bond activations.

Stoichiometry

10.1021/ja409049t

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Citations (51)

Reiner Keller, Doing discourse research: An introduction for social scientists. Trans. by Bryan Jenner. Los Angeles: SAGE, 2013. Pp. 176. Hb. £24.99.

Language in Society (2016)

Zhong‐Ming Sun Hongyan Zhang

An abstract is not available for this content so a preview has been provided. Please use the Get access link above for information on how to access this content.

10.1017/s0047404515000895

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