Robert C. Kerber

Stony Brook University

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Oskar Nuyken

München Klinik

Nathan Kornblum

Purdue University West Lafayette

W. Ast

Technical University of Munich

Daniel J. Ehntholt

TIAX (United States)

Wolfgang Gestrich

Technische Universität Berlin

Rainer Steinhausen

Technical University of Munich

Paul Helquist

University of Notre Dame

Thomas J. Ryan

Maine Medical Center

Jürgen Starnick

Technische Universität Berlin

Thomas M. Davies

Calderdale and Huddersfield NHS Foundation Trust

Cooperative Institutions

Stony Brook University

Technical University of Munich

State University of New York

Purdue University West Lafayette

Technische Universität Berlin

Boston University

Brookhaven National Laboratory

University of Notre Dame

University of California, Los Angeles

Rutgers, The State University of New Jersey

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(eta3-Triphenylcyclopropenyl) tricarbonylcobalt

Inorganic Chemistry (1979)

Tat Chiang Robert C. Kerber S. David Kimball Joseph W. Lauher

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXT(eta3-Triphenylcyclopropenyl) tricarbonylcobaltTat Chiang, Robert C. Kerber, S. David Kimball, and Joseph W. LauherCite this: Inorg. Chem. 1979, 18, 6, 1687–1691Publication Date (Print):June 1, 1979Publication History Published online1 May 2002Published inissue 1 June 1979https://pubs.acs.org/doi/10.1021/ic50196a058https://doi.org/10.1021/ic50196a058research-articleACS PublicationsRequest reuse permissionsArticle Views186Altmetric-Citations39LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InRedditEmail Other access optionsGet e-AlertscloseSupporting Info (1)»Supporting Information Supporting Information Get e-Alerts

10.1021/ic50196a058

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Citations (42)

Benzo Derivatives of Nitrocyclopentadiene

The Journal of Organic Chemistry (1968)

Robert C. Kerber Mary Hodos

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTBenzo Derivatives of NitrocyclopentadieneRobert Kerber and Mary HodosCite this: J. Org. Chem. 1968, 33, 3, 1169–1172Publication Date (Print):March 1, 1968Publication History Published online12 August 2003Published inissue 1 March 1968https://doi.org/10.1021/jo01267a601RIGHTS & PERMISSIONSArticle Views119Altmetric-Citations5LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InReddit PDF (556 KB) Get e-Alerts Get e-Alerts

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10.1021/jo01267a601

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Citations (6)

Thermolyse einiger azoalkylacetate und azochloralkane

Die Makromolekulare Chemie (1982)

Oskar Nuyken Herbert F. Schuster Robert C. Kerber

Abstract The kinetic results (from DSC and 1 H NMR) of the thermolysis of symmetric azochloroalkanes and azoalkyl acetates with the general structure R 1 R 2 (X) C—N=N—C(X) R 1 R 2 (X=OCOCH 3 , Cl; R 1 , R 2 =CH 3 , C 6 H 5 ) and of asymmetric phenylazoalkyl acetates with the general structure R 1 R 2 (H 3 COCO) C—N=N—C 6 H 5 (R 1 R 2 =CH 3 , C 6 H 5 ) are described. The suitability of the asymmetric compounds as initiators for radical polymerization is demonstrated with (diphenyl)phenylazomethyl acetate ( 7c ). Quantitative measurements of the thermolysis products from 1,1′‐azo(methylethyl) diacetate ( 4a ) showed that the ratio for the disproportionation to combination reaction of the resulting substituted alkyl radikals is 4,3.

10.1002/macp.1982.021830713

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Citations (10)

Zum Lösungsmitteleinfluß bei der Bildung von Polystyrolperoxyd

Zeitschrift für Elektrochemie Berichte der Bunsengesellschaft für physikalische Chemie (1959)

Robert C. Kerber

Abstract Die Kinetik der Polystyrolperoxydbildung wird unter Verwendung verschiedener Lösungsmittel unter‐sucht. Dabei zeigt sich eine Abhängigkeit der Bruttoreaktionsgeschwindigkeit von der Dielektrizitätskonstante des Lösungsmittels. Eine Erhöhung der DK im Reaktionssystem ist ganz allgemein auch mit einer Erhöhung der Sauerstoffaufnahmegeschwindigkeit verbunden, während Lösungsmittel mit einer DK, die kleiner ist als die des monomeren Styrols, eine ganz ausgeprägte Verlangsamung der Reaktion bewirken. Es werden verschiedene Möglichkeiten für die Beeinflussung der einzelnen Teilreaktionen durch die DK des Lösungsmittels diskutiert. Die erhaltenen experimentellen Ergebnisse lassen sich zumindest qualitativ deuten, wenn man die Ansätze von Alfrey und Price, die für die Behandlung von Kopolymerisationssystemen aufgestellt wurden, anwendet. Dabei wird lediglich die Wechselwirkung effektiver Ladungen im Übergangszustand als durch die DK des Lösungsmittels beeinflußbar angenommen. Andere Effekte, die durch die Verschiedenheit der Lösungsmittel hervorgerufen werden können, scheinen nur von sekundärer Bedeutung für die Geschwindigkeit der Bruttoreaktion zu sein.

10.1002/bbpc.19590630224

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Citations (2)

ChemInform Abstract: MECHANISM OF CYCLOADDITION OF NITROSO COMPOUNDS WITH DIPHENYLKETENE

Chemischer Informationsdienst (1974)

Robert C. Kerber Michael C. Cann

10.1002/chin.197449255

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More on the Nature of Resonance (the author replies)

Journal of Chemical Education (2006)

Robert C. Kerber

ADVERTISEMENT RETURN TO ISSUEPREVLetterNEXTMore on the Nature of Resonance (the author replies)Robert C. Kerber View Author Information Chemistry Department, State University of New York at Stony Brook, Long Island, NY 11794-3400Cite this: J. Chem. Educ. 2006, 83, 9, 1291Publication Date (Web):September 1, 2006Publication History Received3 August 2009Published online1 September 2006Published inissue 1 September 2006https://doi.org/10.1021/ed083p1291RIGHTS & PERMISSIONSArticle Views348Altmetric-Citations1LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InReddit PDF (84 KB) Get e-AlertsSUBJECTS:Delocalization,Resonance structures Get e-Alerts

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10.1021/ed083p1291

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Citations (1)

Zum copolymerisationsverhalten des 1,3,5‐triacryloylhexahydro‐1,3,5‐triazins

Die Makromolekulare Chemie (1989)

Robert C. Kerber Klaus Pöllmann Heidi Samarian Peter Sluka

Abstract Radical homo‐ and copolymerizations of 1,3,5‐triacryloylhexahydro‐1,3,5‐triazine ( 1 ) with methyl methacrylate (MMA), styrene (S) and a ‐methylstyrene (MS) were investigated at 60°C in DMF, varying the total concentrations of the monomers as well as the contents of 1 . The monomer reactivity ratios were evaluated using the copolymer composition obtained by elemental analysis, according to the Kelen‐Tüdős method applying the equation of Gibbs. The resulting values for the system 1/MMA , based on the concentration of the CC double bonds, are: r 1 = 0,50, r MMA = 1,76 and for the system 1 /S: r 1 = 0,17, r S = 1,03. Furthermore, the double bond content of the copolymers was determined by thiophenol addition showing a significant variation with the overall monomer concentration in the reaction mixtures concerned. This fact has to be considered when calculating the real monomer reactivity ratios yielding in the case of the system 1 /S the values r 1 = 0,43 and r S = 0,41.

Reactivity

Thiophenol

Triazine

10.1002/macp.1989.021901133

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Über die Eigenschaften einiger wasserlöslicher Azo‐Initiatoren

Die Makromolekulare Chemie (1978)

Oskar Nuyken Robert C. Kerber

Abstract Water soluble azo compounds of the structure 1a, b, 2a, b, 3, 4 , and 5 decompose, depending on the substitution of the aromatic ring, in water already at room temperature. Therefore, they are useful initiators for solution and emulsion polymerisations in this temperature region. Reactions competing with thermolysis, as the formation of a hydrazone (pH>8) and ionic reactions with suitable reagents (phenols) are described.

Hydrazone

10.1002/macp.1978.021791204

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Citations (18)

ChemInform Abstract: KINETIK DES THERMISCHEN ZERFALLS EINIGER UNSYMMETRISCHER AZOVERBINDUNGEN DER STRUKTUR AR‐N=N‐C(CH3)2(NO2)

Chemischer Informationsdienst (1975)

Robert C. Kerber Oskar Nuyken Ludwig Weithmann

oskar

10.1002/chin.197528139

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6,6-Dicyclopropylfulvene

The Journal of Organic Chemistry (1966)

Robert C. Kerber Harold Linde

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXT6,6-DicyclopropylfulveneRobert C. Kerber and Harold G. Linde Jr.Cite this: J. Org. Chem. 1966, 31, 12, 4321–4322Publication Date (Print):December 1, 1966Publication History Published online1 May 2002Published inissue 1 December 1966https://pubs.acs.org/doi/10.1021/jo01350a553https://doi.org/10.1021/jo01350a553research-articleACS PublicationsRequest reuse permissionsArticle Views124Altmetric-Citations12LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InRedditEmail Other access optionsGet e-Alertsclose Get e-Alerts

10.1021/jo01350a553

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Citations (13)