Sébastien Floquet

Institut Lavoisier de Versailles

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Emmanuel Cadot

Institut Lavoisier de Versailles

129

Mohamed Haouas

Institut Lavoisier de Versailles

Jérôme Marrot

Centre National de la Recherche Scientifique

Emmanuel Terazzi

Saarland University

Claude Piguet

University of Geneva

Maxim N. Sokolov⧫

Novosibirsk State University

Laure Guénée

University of Geneva

Jean‐François Lemonnier

University of Manchester

Thibault Dutronc

University of Geneva

Pavel A. Abramov⧫

Nikolaev Institute of Inorganic Chemistry

Cooperative Institutions

Centre National de la Recherche Scientifique

179

Université Paris-Saclay

Institut Lavoisier de Versailles

Université de Versailles Saint-Quentin-en-Yvelines

Université Paris-Sud

University of Geneva

Université Paris Cité

Nikolaev Institute of Inorganic Chemistry

Sorbonne Université

Institut de Chimie Moléculaire et des Matériaux d'Orsay

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A New Oxomolybdate Component Extracted from the “Virtual Dynamic Library” Yielding the Macrocyclic Anion [(Mo^VI₈O₂₈)₄(Mo^V₂O₂S₂)₄]²⁴⁻

Inorganic Chemistry (2010)

Vladimir S. Korenev Antoine G. Boulay Anne Dolbecq Maxim N. Sokolov⧫Akram Hijazi

A rare isomer of the {Mo(8)O(28)}(8-) anion has been trapped from an acidified aqueous solution of molybdate by using the {Mo(2)O(2)S(2)}(2+) oxothio cation as the linker and isolated as a part of a unique macrocyclic anion, which consists of four isopolyoxomolybdate fragments {Mo(8)O(28)} bridged by four {Mo(2)O(2)S(2)} units.

Linker

Component (thermodynamics)

10.1021/ic101545w

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Citations (17)

Predictions, Synthetic Strategy, and Isolation of a Linear Tetrametallic Triple‐Stranded Lanthanide Helicate

Angewandte Chemie International Edition (2005)

Kornelia Zeckert Josef Hamáček Jean‐Michel Senegas Natalia Dalla‐Favera Sébastien Floquet

Complex twists: Following theoretical thermodynamic predictions, it is seen that the tetrametallic triple-stranded lanthanide helicate [Ln4L3]12+ (see structure) dominates the speciation in solution at millimolar concentrations, despite its high positive charge. Isolation of the europium complex in the solid state unambiguously establishes its nanometric triple-helical structure.

Europium

Genetic algorithm

Isolation

10.1002/anie.200503040

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Citations (87)

CCDC 946492: Experimental Crystal Structure Determination

The Cambridge Structural Database (2013)

Fatma Bannani Sébastien Floquet Nathalie Leclerc‐Laronze Mohamed Haouas Françis Taulelle

An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures.

10.5517/cc10rx0p

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Citations (0)

CCDC 226787: Experimental Crystal Structure Determination

The Cambridge Structural Database (2004)

Sébastien Floquet M.C. Muñoz Éric Rivière René Clément Jean-Paul Audière

10.5517/cc7lzqh

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Citations (0)

CCDC 962490: Experimental Crystal Structure Determination

The Cambridge Structural Database (2014)

Sébastien Floquet Souhaël Draoui Jérôme Marrot Franck Millange Michel Frigoli

Crystal (programming language)

10.5517/cc119k2z

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Citations (0)

CSD 1559984: Experimental Crystal Structure Determination

The Cambridge Structural Database (2017)

Mhamad Aly Moussawi Sébastien Floquet Pavel A. Abramov⧫Cristian Vicent Mohamed Haouas

10.5517/ccdc.csd.cc1pc92f

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Synthesis, Structures, and Solution Studies of a New Class of [Mo₂O₂S₂]-Based Thiosemicarbazone Coordination Complexes

ACS Omega (2022)

Arcadie Fuior Diana Cebotari Mohamed Haouas Jérôme Marrot Guillermo Mı́nguez Espallargas

This paper deals with the synthesis, structural studies, and behavior in solution of unprecedented coordination complexes built by the association of a panel of 14 representative thiosemicarbazone ligands with the cluster [Mo2O2S2]2+. These complexes have been thoroughly characterized both in the solid state and in solution by XRD and by NMR, respectively. In particular, HMBC 1H{15N} and 1H DOSY NMR experiments bring important elements for understanding the complexes' behavior in solution. These studies demonstrate that playing on the nature and the position of various substituents on the ligands strongly influences the coordination modes of the ligands as well as the numbers of isomers in solution, mainly 2 products for the majority of complexes and up to 5 for some of them.

Semicarbazone

Coordination complex

Coordination number

10.1021/acsomega.2c00705

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Citations (11)

CCDC 870372: Experimental Crystal Structure Determination

The Cambridge Structural Database (2013)

Hani El Moll J.C. Kemmegne-Mbougen Mohamed Haouas F. Taulelle Jérôme Marrot

10.5517/ccy6pjb

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{Mo 2 O 2 S 2 } 2+ -directed synthesis of a polyoxotungstoarsenate(III). Structure and 183 W NMR studies of the [(⍺–AsW 9 O 33 ) 3 (WO(OH 2 )) 3 (Mo 2 O 2 S 2 (H 2 O) 4 )] 13− anion

Marie‐Anne Pilette Jérôme Marrot Sylvain Duval Fatma Bannani Sébastien Floquet

Source

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Exothermal effects in the thermal decomposition of [IrCl₆]²⁻-containing salts with [M(NH₃)₅Cl]²⁺ cations: [M(NH₃)₅Cl][IrCl₆] (M = Co, Cr, Ru, Rh, Ir)

New Journal of Chemistry (2017)

S. A. Martynova Pavel E. Plyusnin Tatyana I. Asanova Igor Asanov Denis P. Pishchur

[M(NH₃)₅Cl][IrCl₆], M = Co, Cr, Ru, Rh, and Ir, were proposed as single-source precursors for bimetallic alloys. Upon heating, compounds show endothermic effect which can be corresponded with Ir(iv) reduction and ligand exchange.

Bimetallic strip

Endothermic process

10.1039/c7nj04035k

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Citations (14)