Bimetallic nanoparticles have received much attention recently due to their multifunctional applications, and synergistic potential at low concentrations. In the current study, bimetallic boron oxide-zinc oxide nanoparticles (B
ABSTRACT Energy‐efficient semiconducting BaS:MnS:Sb 2 S 5 has been synthesized using a single source precursor method. The resulting dithiocarbamate metallic sulfide has an average crystallite size of 17.77 nm and a small band gap of 3.82 eV. A functional group investigation revealed the presence of several bonds, including the metal sulfide bond. This sulfide exhibited a double‐step thermal breakdown pattern. BaS:MnS:Sb 2 S 5 particles were formed like cubes and tended to form cube‐like formations. The electrochemical charge‐storing behavior of BaS:MnS:Sb 2 S 5 was investigated using a nickel foam electrode and a sulfide slurry. The fabricated electrode demonstrated a satisfactory capacity for charge storage, with a specific capacitance of 762.83 F g −1 . This indicates a substantial amount of potential for long‐term energy storage utilizing electrodes. This electrode has a specific power density of 9084.78 W kg −1 and a low series resistance of ( R s ) = 0.71 Ω, as per impedance measurements. Electro‐catalysis produced an OER overpotential and a corresponding Tafel slope of 233 mV and 157 mV/dec from the electrode. Conversely, for HER activity, the obtained overpotential and subsequent Tafel slope were 386 mV and 73 mV dec −1 , respectively.
Correction for ‘Unveiling anticancer, antimicrobial, and antioxidant activities of novel synthesized bimetallic boron oxide–zinc oxide nanoparticles’ by Amr H. Hashem et al. , RSC Adv. , 2023, 13 , 20856–20867, https://doi.org/10.1039/D3RA03413E.
Corynebacterium glutamicum is an authenticated microorganism that supports amino acid production consistent with dietary importance. Fermentation parameters like temperature, agitation speed, and carbon source concentration were optimized using response surface methodology. Surface response model suggested that optimal fermentation parameters including 30°C, 50 g/L glucose concentration, and shaking speed of 120 rpm furnished 14.2 g/L of glutamic acid and 5.1 g/L lysine, comparable with the predicted values. After optimizing fermentation parameters in shake flasks, the fermentation kinetics was studied in a stirred fermenter. The kinetic study revealed that the substrate consumption rate achieved a maximum level of 3.36 g/L/hour between 12 and 18 hours; afterwards, it decreased and fell to 1.9 g/L/hour. Average biomass yield over a period of 48 hours was 0.337 g/L; however, maximum biomass yield of 0.51 g/L was noted between 10 and 20 hours. Overall molar yield coefficient of CO 2 () was found to be 0.234. The molar yield coefficient of biomass () was 0.6 in exponential phase which decreased afterwards. This study indicates that the average biomass yield over a time of 48 hours was 0.337 g/L, with a maximum yield within 10 to 20 hours obtained under optimized conditions. The molar yield coefficient of CO 2 () was found to be 0.234. The molar yield coefficient of biomass () was 0.6 in exponential phase which decreased and fell to near zero at 48 hrs.
Abstract This study discusses the micro‐level structural details of Cichorieae pollen sources elucidated by scanning electron microscopy (SEM) and explains their symmetry and morphometry. The in‐depth knowledge from the electron ultrastructure of Asteraceae pollen has provided insights into enhanced pollen morphology, and the antimicrobial significance of species under study presents novel avenues for their natural defense mechanisms in the development of antimicrobial agents. In this research, both quantitative and qualitative features of pollen were examined. The pollen grains are prolate‐spheroidal and oblate‐spheroidal in shape, characterized by a maximum polar diameter of 55.6–61.0 μm and a maximum equatorial distance of 68.3–74.4 μm. SEM reveals various configurations such as echinate perforate‐tectate, psilate, and echino‐lophate perforate. The Cichorieae species have significant antimicrobial efficacy and are promising sources for the development of novel antimicrobial drugs with potential implications in pharmaceutical and healthcare industries. SEM analysis of Cichorieae pollens has provided remarkable insights into their unique structures, revealing diverse shapes and surface ornamentations, which can be used for accurate Asteraceae species identification. Research Highlights SEM provides unique pollen surface structures and patterns of Chicory pollen grains. Chemical composition of Chicory botanical sources provides valuable information on their potential as antimicrobial agents. SEM imaging reveals specialized fenestrate grain structures of taxonomic importance.
Head and neck squamous cell carcinoma (HNSC) is one of the most lethal malignancies around the globe. Due to its complex nature, the diagnostic and prognostic signatures of HNSC remain poorly understood. This study was launched to identify signature genes and their signaling pathways related to the development of HNSC. In the current study, we retrieved the GSE53819 dataset from the Gene Expression Omnibus (GEO) database to determine the differentially expressed genes (DEGs) using the "Limma" R package. Adjusted P values P < 0.05 and |logFC| ≥ 1 were selected as the filtering conditions. To identify hub genes, the protein-protein interaction (PPI) network construction of the DEGs was performed using STRING. We further used UALCAN, GEPIA, OncoDB, GENT2, MEXPRESS, and HPA databases for the expression, validation, survival, and methylation analyses of the hub genes. The cBioPortal tool was used to investigate the genetic alterations in hub genes. CancerSEA, TIMER, DAVID, ENCORI, and DrugBank were also used to explore a few more hub gene-associated parameters. Lastly, HOK, FaDu, and SCC25 cell lines were used to validate hub gene expression via RNA sequencing (RNA-seq) technique. A total of top 250 DEGs were selected for detailed analysis in this study. From these DEGs, prognostic and diagnostic associated four hub genes, which could serve as potential molecular biomarkers and therapeutic targets in HNSC patients were identified. Four hub genes, including down-regulated DNAH1 and DNALI1, while up-regulated DNAH9 and CCDC151 were strongly implicated in HNSC. We also validated the same expression pattern of the hub genes using RNA-seq analysis in HNSC and normal cell lines. Moreover, this study also revealed some novel links between DNAH1, DNALI1, DNAH9, and CCDC151 expression and genetic alterations, promoter methylation status, immune cell infiltration, miRNAs, gene enrichment terms, and various chemotherapeutic drugs. In conclusion, we indicated four hub genes (DNAH1, DNALI1, DNAH9, and CCDC151) and their associated signaling pathways, which may improve our understanding of HNSC and could be used as new therapeutic targets.
The twisted spiro-type SAM 4PA-spiro effectively suppresses molecular aggregation and ensures appropriate energy levels, providing an efficiency of 25.28 and 21.87% for the p–i–n PSCs (0.05 cm 2 ) and modules (29.0 cm 2 ).