Aurelio Mateo‐Alonso

Polymat

Author Statistics

Papers

Citation

H-Index

i-10 index

Research Trends

Author Order

Document Type

Co-Authors

Manuel Melle‐Franco

University of Aveiro

111

Akinori Saeki

Osaka University

Maurizio Prato

National Interuniversity Consortium of Materials Science and Technology

Karol Strutyński

University of Aveiro

Diego Cortizo‐Lacalle

Polymat

Marta Martínez‐Abadía

Polymat

Marco Carini

CIC biomaGUNE

Dirk M. Guldi

Friedrich-Alexander-Universität Erlangen-Nürnberg

Cristian Gozálvez

University of the Basque Country

Juan P. Mora‐Fuentes

Universidad de Granada

Cooperative Institutions

University of the Basque Country

Centre National de la Recherche Scientifique

Polymat

Ayuntamiento de San Sebastián

Friedrich-Alexander-Universität Erlangen-Nürnberg

TU Dresden

University of Bologna

University of Trieste

National Interuniversity Consortium of Materials Science and Technology

Chinese Academy of Sciences

Author Statistics

Papers

Citation

H-Index

i-10 index

Research Field

Twisted pyrene-fused azaacenes

Chemical Communications (2014)

Sandeep More Sunil Choudhary Alexander Higelin Ingo Krossing Manuel Melle‐Franco

An approach for introducing twists in pyrene-fused azaacenes is reported. Depending on the volume and the rigidity of the silyl groups, different-sized twist angles, which oscillate between 4° and 24°, are induced along the longitudinal conjugated backbone.

Rigidity (electromagnetism)

Structural rigidity

10.1039/c3cc48742c

Cite

Citations (62)

Accelerated iterative synthesis of ultralong graphene nanoribbons with full atomic precision

Chem (2023)

Rajeev K. Dubey Mauro Marongiu Shuai Fu Guanzhao Wen Mischa Bonn

Heteroatom

10.1016/j.chempr.2023.06.017

Cite

Citations (11)

Stabilization of fulleropyrrolidine N-oxides through intrarotaxane hydrogen bonding

Chemical Communications (2007)

Aurelio Mateo‐Alonso P. Brough Maurizio Prato

The chemical stabilization of labile fulleropyrrolidine N-oxides is achieved by encapsulation through intrarotaxane hydrogen bonding.

10.1039/b617835a

Cite

Citations (38)

Giant Star‐Shaped Nitrogen‐Doped Nanographenes

Angewandte Chemie (2018)

Juan P. Mora‐Fuentes Alberto Riaño Diego Cortizo‐Lacalle Akinori Saeki Manuel Melle‐Franco

Abstract Star‐shaped nanographenes (SNGs) are large monodisperse polycyclic aromatic hydrocarbons that are larger than a nanometer and have shown a lot of promise in a wide range of applications including electronics, energy conversion, and sensing. Herein, we report a new family of giant star‐shaped N‐doped nanographenes with diameters up to 6.5 nm. Furthermore, the high solubility of this SNG family in neutral organic solvents at room temperature allowed a complete structural, optoelectronic, and electrochemical characterisation, which together with charge transport studies illustrate their n‐type semiconducting character.

Nanometre

Star (game theory)

Dispersity

Organic Electronics

10.1002/ange.201811015

Cite

Citations (16)

CCDC 1497466: Experimental Crystal Structure Determination

The Cambridge Structural Database (2016)

Gabriella Antonicelli Cristian Gozálvez Ainhoa Atxabal Manuel Melle‐Franco Luis E. Hueso

An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures.

Crystal (programming language)

10.5517/ccdc.csd.cc1m87ch

Cite

Citations (0)

Electrostatic layer-by-layer construction and characterization of photoelectrochemical solar cells based on water soluble polythiophenes and carbon nanotubes

Journal of Materials Chemistry (2009)

Vito Sgobba Anna Troeger Rita Cagnoli Aurelio Mateo‐Alonso Maurizio Prato

Positively and negatively charged functionalized polythiophenes and single walled carbon nanotubes were sequentially adsorbed on indium tin oxide electrodes by electrostatic and van der Waals interactions using the layer-by-layer deposition method. The resulting donor/acceptor photoelectrodes were tested as photoelectrochemical cells. Upon illumination, monochromatic incident photoconversion efficiencies of 8.2 and 4.3% were determined for eight stacks of single walled carbon nanotubes with ammonium and sulfonate polythiophene derivatives, respectively.

Polythiophene

Indium tin oxide

Acceptor

10.1039/b902712m

Cite

Citations (38)

Readily Processable Hole‐Transporting Peropyrene Gels

Angewandte Chemie International Edition (2018)

Marta Martínez‐Abadía Gabriella Antonicelli Akinori Saeki Aurelio Mateo‐Alonso

Abstract The development of organic electronics requires scalable solution‐processing methods that enable the fabrication of electronic devices over large areas at low cost. The preparation of peropyrene gels constituted of 3D networks of entangled 1D ribbon‐like fibrils that extend over the μm scale are now reported. OFETs were easily fabricated by depositing the gels in the sol state over bottom‐gate bottom‐contact transistors and by allowing its gelation thereafter. Electrical characterisation of such field‐effect transistors shows a good balance between processability and performance with hole mobilities that are two orders of magnitude higher than those observed in thin films obtained from non‐gelating solvents under the same conditions.

Ribbon

Organic Electronics

10.1002/anie.201804453

Cite

Citations (17)

Structural Approaches to Control Interlayer Interactions in 2D Covalent Organic Frameworks

Advanced Materials (2020)

Marta Martínez‐Abadía Aurelio Mateo‐Alonso

The ability to design and synthesize monomers can affect fundamental aspects in 2D covalent organic frameworks, such as dimensionality, topology, and pore size. Besides this, the structure of the monomers can also affect interlayer interactions, which provide an additional means to influence crystallinity, layer arrangement, interlayer distances, and exfoliability. Herein, some of the effects that the structure of monomers can have on the interlayer interactions in 2D covalent organic frameworks and related materials are illustrated.

10.1002/adma.202002366

Cite

Citations (87)

Increasing and dispersing strain in pyrene-fused azaacenes

Chemical Communications (2020)

Javier Mateos‐Martín Marco Carini Manuel Melle‐Franco Aurelio Mateo‐Alonso

A new strategy to obtain distorted pyrene-fused azaacenes is reported. The careful alignment and selection of substituents give rise to highly twisted pyrene-fused azaacenes. A combined global and local theoretical analysis shows how the strain is generated and dispersed across the aromatic backbone. Furthermore, simulation of the observed optoelectronic properties shines light on the structural factors that govern the properties of twisted pyrene-fused azaacenes.

Strain (injury)

10.1039/d0cc04735j

Cite

Citations (8)

Synthesis of Fullerene‐Stoppered Rotaxanes Bearing Ferrocene Groups on the Macrocycle

European Journal of Organic Chemistry (2010)

Aurelio Mateo‐Alonso Maurizio Prato

Abstract The synthesis, characterisation and behaviour of a series of rotaxanes containing a fulleropyrrolidine stopper and two ferrocene moieties on the macrocycle is reported. Remarkably, the presence of large and bulky ferrocene groups does not interfere either in the synthesis or in the translocation of the macrocycle induced by π–π interactions between the macrocycle and the fullerene. The synthetic routes developed can also be applied to the preparation of rotaxane scaffolds that can be complexed to [Ru(CO)TPP] by axial coordination. Overall, the synthetic routes presented herein provide an efficient way to prepare a variety of rotaxanes and molecular shuttles with potential applications in different fields.

Rotaxane

Molecular machine

10.1002/ejoc.200901309

Cite

Citations (21)