Mikiko Sodeoka

RIKEN

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Co-Authors

Masakatsu Shibasaki

Microbial Chemistry Research Foundation

Yoshitaka Hamashima

University of Shizuoka

Kosuke Dodo

RIKEN Center for Sustainable Resource Science

Go Hirai

Kyushu University

Daisuke Hashizume

RIKEN Center for Emergent Matter Science

Yoshihiro Sohtome

Pioneer (Japan)

Hiromichi Egami

University of Shizuoka

Katsumasa Fujita

Osaka University

Shintaro Kawamura

RIKEN Center for Sustainable Resource Science

Hiroyuki Koshino

RIKEN

Cooperative Institutions

RIKEN

169

The University of Tokyo

154

Tohoku University

103

RIKEN Advanced Science Institute

Osaka University

Kyoto University

Japan Science and Technology Agency

RIKEN Center for Sustainable Resource Science

Hokkaido University

Kyushu University

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ChemInform Abstract: Highly Efficient Synthesis of Carbacyclin Analogue. Stereospecific Synthesis of Aryl‐Substituted Exocyclic Olefin.

ChemInform (1988)

Mikiko Sodeoka Soichirou Satoh Masakatsu Shibasaki

Abstract The stereoselective synthesis of aryl‐substituted exocyclic olefins is achieved starting from the corresponding aldehydes via the reaction conditions A) and B).

Stereospecificity

10.1002/chin.198845119

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Citations (0)

Unnatural enantiomer of chaetocin shows strong apoptosis-inducing activity through caspase-8/caspase-3 activation

Bioorganic & Medicinal Chemistry Letters (2010)

Yuou Teng Katsuya Iuchi Eriko Iwasa Shinya Fujishiro Yoshitaka Hamashima

Natural product

Caspase 8

Caspase-9

10.1016/j.bmcl.2010.07.032

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Citations (32)

Stereospecific synthesis of exo-allylic alcohol. An efficient asymmetric synthesis of (R)-(-)-2-acetyl-5,8-dimethoxy-1,2,3,4-tetrahydro-2-naphthols

Tetrahedron Letters (1985)

Mikiko Sodeoka Takamasa Iimori Masakatsu Shibasaki

Stereospecificity

Sharpless epoxidation

Allylic alcohol

10.1016/s0040-4039(00)99036-1

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Citations (25)

CCDC 895188: Experimental Crystal Structure Determination

The Cambridge Structural Database (2012)

Masaki Morita G Hirai M. Ohkubo Hiroyuki Koshino Daisuke Hashizume

An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures.

10.5517/ccz1j1k

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Citations (0)

ChemInform Abstract: Unique Features of Chiral Palladium Enolates Derived from β‐Ketoamide: Structure and Catalytic Asymmetric Michael and Fluorination Reactions.

ChemInform (2015)

Kenji Hayamizu Naoki Terayama Daisuke Hashizume Kosuke Dodo Mikiko Sodeoka

Abstract Chiral Pd‐BINAP complexes catalyze enantioselective Michael and fluorination reactions of β‐ketoamides and β‐ketoesters in which Pd‐enolate intermediates play a key role.

Michael reaction

BINAP

10.1002/chin.201550025

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Author response: METTL18-mediated histidine methylation of RPL3 modulates translation elongation for proteostasis maintenance

Eriko Suzuki Tadahiro Shimazu Mari Takahashi Kaoru Kotoshiba Takehiro Suzuki

Proteostasis

Elongation

10.7554/elife.72780.sa2

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Citations (1)

Pd(II)-Catalyzed Asymmetric Fluorination of α-Aryl-α-cyanophosphonates with the Aid of 2,6-Lutidine

Synlett (2007)

Mikiko Sodeoka Kenichi Moriya Yoshitaka Hamashima

We describe herein the catalytic asymmetric fluorination of α-cyanophosphonates using chiral Pd(II)-bisphosphine complexes. While metal complexes failed to promote the reaction alone, a reaction system involving Pd(II) and organic base such as 2,6-lutidine was developed. The Pd(II) complex activates the substrates through coordination of the nitrile group, and 2,6-lutidine abstracts an acidic proton, thereby affording the desired fluorinated products in good yields with up to 78% ee. The products may be useful as novel physiological phosphate mimics in medicinal chemistry.

Base (topology)

10.1055/s-2007-977437

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Citations (11)

Slit-scanning confocal Raman microscopy: Practical applications in live cell imaging

Almar F. Palonpon Masaya Okada Jun Ando Hiroyuki Yamakoshi Kosuke Dodo

Raman microscopy is recognized as a powerful tool but not yet practical for live cell imaging because of long acquisition times. Using a slit-scanning Raman microscope, we demonstrate realistic applications in live cell imaging.

Raman microscope

Live cell imaging

Slit

10.1109/iqec-cleo.2011.6193906

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ChemInform Abstract: Catalytic Asymmetric Aldol Reaction via Chiral Pd(II) Enolate in Wet DMF.

ChemInform (1995)

Mikiko Sodeoka Kazuhiko Ohrai Masakatsu Shibasaki

Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.

Aldol reaction

10.1002/chin.199537030

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Citations (1)

Acid-base catalysis using chiral palladium complexes

Pure and Applied Chemistry (2006)

Mikiko Sodeoka Yoshitaka Hamashima

Abstract Chiral Pd aqua and µ-hydroxo complexes were found to act as mild Brønsted acids and bases, and chiral Pd enolates were generated from these complexes even under acidic conditions. Highly enantioselective Michael addition, Mannich-type reaction, fluorination, and conjugate addition of amines have been developed based on the acid-base character of these Pd complexes.

Conjugate

Base (topology)

Brønsted–Lowry acid–base theory

10.1351/pac200678020477

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Citations (40)