Single-component porous silk microcapsules were synthesized by the one-step desolvation method using PLGA spheres as sacrificial templates. Subsequently, AuNRs–T5 were utilized to synthesize silk-based hybrid capsules, which not only capped the pores of the shell but also enhanced Raman scattering.
Purpose This paper aims to study the effect of temperature on the process and kinetic parameters of the hydrogen evolution reaction of X80 under cathodic protection (CP) in 3.5% NaCl solution. Design/methodology/approach Potentiodynamic polarization combined with the hydrogen permeation test is used to analyze the hydrogen evolution reaction (HER) process and the rate-determining step for which is diagnosed through the electrochemical impedance spectrum method. Then, the influence of temperature on kinetic parameters of HER can be known from the results obtained by using the Iver-Pickering-Zamenzadeh model for data analysis. Findings The results show that the HER proceeds through Volmer–Tafel route with the Volmer reaction acting as the rate-controlling step; Increasing temperature gives a higher activity of the HER on X80, it also accelerates the hydrogen desorption and diffusion of hydrogen into the metal. Originality/value There exist few studies on the topic of how temperature affects the HER process. It is imperative to conduct a relevant study to give some instruction in cathodic protection system design and this paper fulfills this need.
Liquid and gas interactions often produce bubbles that stay for a long time without bursting on the surface, making a dry foam structure. Such long lasting bubbles simulated by the level set method can suffer from a small but steady volume error that accumulates to a visible amount of volume change. We propose to address this problem by using the volume control method. We track the volume change of each connected region, and apply a carefully computed divergence that compensates undesired volume changes. To compute the divergence, we construct a mathematical model of the volume change, choose control strategies that regulate the modeled volume error, and establish methods to compute the control gains that provide robust and fast reduction of the volume error, and (if desired) the control of how the volume changes over time.
Molecular weight is an important parameter for not only describing polymer property but also influencing polymer flooding effect. The reservoir property and development status of medium-low permeable reservoirs in Daqing Oil Field are different from the major reservoirs. Using the determination method of polymer in major reservoirs will have much error for polymer selection. This paper proposes a new quantitative method for optimizing suitable polymer according to the effect of polymer on incremental recovery value and polymer controlled degree so as to provide evidence for field application.
A phase-field model is used to capture the surfactant-driven formation of fracture patterns in particulate monolayers. The model is intended for the regime of closely-packed systems in which the mechanical response of the monolayer can be approximated as that of a linearly elastic solid. The model approximates the loss in tensile strength of the monolayer with increasing surfactant concentration through the evolution of a damage field. Initial-boundary value problems are constructed and spatially discretized with finite element approximations to the displacement and surfactant damage fields. A comparison between model-based simulations and existing experimental observations indicates a qualitative match in both the fracture patterns and temporal scaling of the fracture process. The importance of surface tension differences is quantified by means of a dimensionless parameter, revealing thresholds that separate different regimes of fracture. These findings are supported by newly performed experiments that validate the model and demonstrate the strong sensitivity of the fracture pattern to differences in surface tension.
A phase-field model is used to capture the surfactant-driven formation of fracture patterns in particulate monolayers. The model is intended for the regime of closely-packed systems in which the mechanical response of the monolayer can be approximated as a linearly elastic solid. The model approximates the loss in tensile strength of the monolayer as the surfactant concentration increases through the evolution of a damage field. Initial-boundary value problems are constructed and spatially discretized with finite element approximations to the displacement and surfactant damage fields. A comparison between model-based simulations and existing experimental observations indicates a qualitative match in both the fracture patterns and temporal scaling of the fracture process. The importance of surface tension differences is quantified by means of a dimensionless parameter, revealing thresholds that separate different regimes of fracture. These findings are supported by newly performed experiments that validate the model and demonstrate the strong sensitivity of the fracture pattern to differences in surface tension.
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