Abstract Volatile organic compounds (VOCs) are carbon‐containing chemicals that may evaporate rapidly at room temperature and standard pressure. Such organic compounds can be preserved inside carbonaceous chondrite matrices. However, unlike meteoritic soluble organic matter (SOM) and insoluble organic matter (IOM), VOCs are typically lost (at least in part) during sample processing (meteorite crushing) and exposure to terrestrial atmosphere and/or solvents. Like SOM and IOM, VOCs can provide valuable insights into the chemical inventory of the meteorite parent body and even the presolar cloud from which our solar system formed, as well as the composition and processes that occurred during the early formation of our solar system and the asteroidal stage. Thus, in this work, we designed and built an instrument that allowed us to access the VOCs present in samples of the carbonaceous chondrites Murchison and Sutter's Mill after mineral disaggregation by means of freeze–thaw cycling. We simultaneously evaluated the abundances and compound‐specific 13 C‐distributions of the volatiles evolving after meteorite powdering at ~20, 60, and 100°C. Carbon monoxide (CO) and methane (CH 4 ) were released from these meteorites as the most abundant VOCs. They were combusted together for analysis and showed positive δ 13 C values, indicative of their extraterrestrial origins. Carbon dioxide (CO 2 ) was also an abundant VOC in both meteorites, and its isotopic values suggest that it was mainly formed from dissolved carbonates in the samples. We also detected aldehydes, ketones, and aromatic compounds in low amounts. Contrary to Murchison, which mostly yielded VOCs with positive δ 13 C values, Sutter's Mill yielded VOCs with negative δ 13 C values. The less enriched 13 C isotope composition of the VOCs detected in Sutter's Mill suggest that they are either terrestrial contaminants, such as VOCs in compressed gas dusters and common laboratory solvents, or compounds disconnected from interstellar sources and/or formed through parent body processing. Understanding the relative abundances and determining the molecular distributions and isotopic compositions of free meteoritic VOCs are key in assessing their extraterrestrial origins and those of chondritic SOM and IOM. Our newly developed technique will be valuable in the study of the samples brought to the Earth from carbonaceous asteroid Bennu by NASA's OSIRIS‐REx mission.
The OSIRIS-REx spacecraft arrived at the near-Earth asteroid (101955) Bennu in December 2018.After operating in proximity for a year, a primary site was selected, and in October 2020, the spacecraft successfully collected a sample.It departed Bennu in May 2021 and is scheduled to return the sample to Earth in September 2023.The OSIRIS-REx mission will bring back various types of samples, including bulk regolith, surface particles adhering to contact pads, witness coupons, the sampler head, and the sample return capsule.The asteroidal material is expected to range in particle size from sub-micron to 3 cm and will be categorized based on size into fines, intermediate, coarse, and large particles.Abundant hydrated silicates, carbonates, magnetite, and organic components are predicted based on remote sensing data.The sample may contain different types of lithic components, such as chondrules, CAIs, and matrix, similar to those found in carbonaceous chondrites.Bennu's surface contains rare material that is non-chondritic and igneous in nature, which may also have been collected.Extensive brecciation was observed at meter-scales, and it is likely to occur at centimeter and finer scales in the sample delivered to Earth.The sample will be analyzed to determine the history of Bennu and its components and precursor asteroid(s).The OSIRIS-REx Sample Analysis Plan (SAP) provides a framework for the science team to meet the Level-1 mission requirement, which includes analyzing the sample to determine the asteroid's presolar history, formation age, nebular and parent-body alteration history, relation to known meteorites, organic history, space weathering, resurfacing history, and energy balance in the regolith.The SAP establishes a hypothesis-driven framework for coordinated sample analyses, defines analytical instrumentation and techniques, and outlines plans for Sample Analysis Readiness Testing.It also provides guidance for the transfer of samples from curation to the sample analysis team, describes the data storage, management, retrieval, and archiving system, and establishes an analysis strategy for different amounts of returned sample, including rare or unique lithologies.
Abstract The exploration of near‐Earth asteroids has revealed dynamic surfaces characterized by mobile, unconsolidated material that responds to local geophysical gradients, resulting in distinct morphologies and boulder distributions. The OSIRIS‐REx (Origins, Spectral Interpretation, Resource Identification, and Security‐Regolith Explorer) mission confirmed that asteroid (101955) Bennu is a rubble pile with an unconsolidated surface dominated by boulders. In this work, we documented morphologies indicative of mass movement on Bennu and assessed the relationship to slope and other geologic features on the surface. We found globally distributed morphologic evidence of mass movement on Bennu up to ~70° latitude and on spatial scales ranging from individual boulders (meter scale) to a single debris flow ~100 m long and several meters thick. The apparent direction of mass movement is consistent with the local downslope direction and dominantly moves from the midlatitudes toward the equator. Mass movement appears to have altered the surface expression of large (≥30m diameter) boulders, excavating them in the midlatitudes and burying them in the equatorial region. Up to a 10 ± 1 m depth of material may have been transported away from the midlatitudes, which would have deposited a layer ~5 ± 1 m thick in the equatorial region assuming a stagnated flow model. This mass movement could explain the observed paucity of small (<50‐m diameter) craters and may have contributed material to Bennu's equatorial ridge. Models of changes in slope suggest that the midlatitude mass movement occurred in the past several hundred thousand years in regions that became steeper by several degrees.
To characterize the ATLO (Assembly, Test, and Launch Operations) environment of the OSIRIS-REx spacecraft, we analyzed 17 aluminum witness foils and two blanks for bacterial, archaeal, fungal, and arthropod DNA. Under NASA's Planetary Protection guidelines, OSIRIS-REx is a Category II outbound, Category V unrestricted sample return mission. As a result, it has no bioburden restrictions. However, the mission does have strict organic contamination requirements to achieve its primary objective of returning pristine carbonaceous asteroid regolith to Earth. Its target, near-Earth asteroid (101955) Bennu, is likely to contain organic compounds that are biologically available. Therefore, it is useful to understand what organisms were present during ATLO as part of the larger contamination knowledge effort-even though it is unlikely that any of the organisms will survive the multi-year deep space journey. Even though these samples of opportunity were not collected or preserved for DNA analysis, we successfully amplified bacterial and archaeal DNA (16S rRNA gene) from 16 of the 17 witness foils containing as few as 7 ± 3 cells per sample. Fungal DNA (ITS1) was detected in 12 of the 17 witness foils. Despite observing arthropods in some of the ATLO facilities, arthropod DNA (COI gene) was not detected. We observed 1,009 bacterial and archaeal sOTUs (sub-operational taxonomic units, 100% unique) and 167 fungal sOTUs across all of our samples (25-84 sOTUs per sample). The most abundant bacterial sOTU belonged to the genus Bacillus. This sOTU was present in blanks and may represent contamination during sample handling or storage. The sample collected from inside the fairing just prior to launch contained several unique bacterial and fungal sOTUs that describe previously uncharacterized potential for contamination during the final phase of ATLO. Additionally, fungal richness (number of sOTUs) negatively correlates with the number of carbon-bearing particles detected on samples. The total number of fungal sequences positively correlates with total amino acid concentration. These results demonstrate that it is possible to use samples of opportunity to characterize the microbiology of low-biomass environments while also revealing the limitations imposed by sample collection and preservation methods not specifically designed with biology in mind.
Abstract Rock breakdown due to diurnal thermal cycling has been hypothesized to drive boulder degradation and regolith production on airless bodies. Numerous studies have invoked its importance in driving landscape evolution, yet morphological features produced by thermal fracture processes have never been definitively observed on an airless body, or any surface where other weathering mechanisms may be ruled out. The Origins, Spectral Interpretation, Resource Identification, and Security–Regolith Explorer (OSIRIS-REx) mission provides an opportunity to search for evidence of thermal breakdown and assess its significance on asteroid surfaces. Here we show boulder morphologies observed on Bennu that are consistent with terrestrial observations and models of fatigue-driven exfoliation and demonstrate how crack propagation via thermal stress can lead to their development. The rate and expression of this process will vary with asteroid composition and location, influencing how different bodies evolve and their apparent relative surface ages from space weathering and cratering records.
Abstract— We present a detailed petrographic and electron microprobe study of metal grains and related opaque minerals in the chondrule interiors and rims of the Bishunpur (LL3.1) ordinary chondrite. There are distinct differences between metal grains that are completely encased in chondrule interiors and those that have some portion of their surface exposed outside of the chondrule boundary, even though the two types of metal grains can be separated by only a few microns. Metal grains in chondrule interiors exhibit minor alteration in the form of oxidized P‐, Cr‐, and Si‐bearing minerals. Metal grains at chondrule boundaries and in chondrule rims are extensively altered into troilite and fayalite. The results of this study suggest that many metal grains in Bishunpur reacted with a type‐I chondrule melt and incorporated significant amounts of P, Cr, and Si. As the system cooled, some metal oxidation occurred in the chondrule interior, producing metal‐associated phosphate, chromite, and silica. Metal that migrated to chondrule boundaries experienced extensive corrosion as a result of exposure to the external atmosphere present during chondrule formation. It appears that chondrule‐derived metal and its corrosion products were incorporated into the fine‐grained rims that surround many type‐I chondrules, contributing to their Fe‐rich compositions. We propose that these fine‐grained rims formed by a combination of corrosion of metal expelled from the chondrule interior and accretion of fine‐grained mineral fragments and microchondrules.
Context. Space weathering changes asteroid surfaces. We know from observations of the Moon and high-albedo asteroids that interplanetary surface processes can alter the spectral properties of silicates. The next step is to extend the study to primitive asteroids. This work supports the OSIRIS-REx mission by providing predictions for what space weathering effects we can expect to find on the mission target: asteroid (101955) 1999 RQ36.
