Antonio Fernández‐Mato

Universidade da Coruña

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Carlos Peinador

Universidade da Coruña

José M. Quintela

Universidade da Coruña

Alessio Terenzi

University of Palermo

Víctor Blanco

IMEC

E. Pia

Universidade da Coruña

Gerardo Blanco

Universidade da Coruña

M.D. Garcia

Universidad Técnica de Ambato

Marcos D. García

Universidade da Coruña

Breogán Pato‐Doldán

Universidad de Extremadura

Daniel Tordera

Universitat de València

Cooperative Institutions

Universidade da Coruña

Universidade de Santiago de Compostela

Universitat de València

Centro Médico Sanitas A Coruña

Centro de Investigación Docencia y Consultoria Administrativa

University of Miami

Parc Científic de la Universitat de València

SINTEF

European Synchrotron Radiation Facility

Norwegian University of Science and Technology

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CCDC 796293: Experimental Crystal Structure Determination

The Cambridge Structural Database (2012)

Antonio Fernández‐Mato José M. Quintela Carlos Peinador

An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures.

10.5517/ccvqlw0

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CCDC 783768: Experimental Crystal Structure Determination

The Cambridge Structural Database (2011)

Víctor Blanco M.D. Garcia Alessio Terenzi E. Pia Antonio Fernández‐Mato

10.5517/ccv9kvj

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Synthesis of new bis(2-[1,8]naphthyridinyl) bridging ligands with multidentate binding sites

Tetrahedron (2008)

Antonio Fernández‐Mato Gerardo Blanco José M. Quintela Carlos Peinador

Synthon

10.1016/j.tet.2008.02.017

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Citations (19)

CCDC 674102: Experimental Crystal Structure Determination

The Cambridge Structural Database (2008)

Antonio Fernández‐Mato Gloria Blanco José M. Quintela Carlos Peinador

10.5517/ccqmg70

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Polymorphism-Triggered Reversible Thermochromic Fluorescence of a Simple 1,8-Naphthyridine

Crystal Growth & Design (2013)

Antonio Fernández‐Mato Marcos D. García Carlos Peinador José M. Quintela Manuel Sánchez‐Andújar

The fluorescent behavior in the solid state of a naphthyridine-based donor–acceptor heterocycle is presented. Synthesized as a crystalline blue-emissive solid (Pbca), the compound can easily be transformed in its P21/c polymorphic form by heating. The latter material shows blue to cyan emission switching triggered by a reversible thermally induced phase transformation. This fact, the reversible acidochromism, and the strong anisotropic fluorescence of the compound in the solid state, account for the potential of 1,8-naphthyridines as simple and highly tunable organic compounds in materials science.

Thermochromism

Cyan

Acceptor

Picric acid

10.1021/cg301656x

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ChemInform Abstract: Convenient One‐Pot Synthesis of Functionalized Thieno[3,2‐d]pyrimidine and Thieno[2,3‐d]pyrimidine Derivatives.

ChemInform (2012)

Antonio Fernández‐Mato Carlos Peinador José M. Quintela

Abstract The procedure allows the synthesis of thienopyrimidinones from phosphazenes (I) and (VII) via reaction with isocyanates followed by addition of a nucleophile.

10.1002/chin.201209177

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Preparation and study of pyridothienopyrazines and their Ruthenium(II) complexes: a new family of bidentate ligands

Tetrahedron (2011)

Antonio Fernández‐Mato José M. Quintela Carlos Peinador Carlos Platas‐Iglesias

10.1016/j.tet.2011.01.066

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ChemInform Abstract: Synthesis and Characterization of Substituted Pyrazino[2′,3′:4,5]thieno[3,2‐d]pyrimidines and Related Molecules.

ChemInform (2011)

Antonio Fernández‐Mato Carlos Peinador José M. Quintela

Abstract Nitrile (III) is used as a convenient starting compound for the synthesis of a variety of fused pyrazine derivatives.

Pyrazine

Characterization

10.1002/chin.201128168

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Metallacycle-Catalyzed S_NAr Reaction in Water: Supramolecular Inhibition by Means of Host–Guest Complexation

The Journal of Organic Chemistry (2014)

Eva M. López‐Vidal Antonio Fernández‐Mato Marcos D. García Moisés Pérez‐Lorenzo Carlos Peinador

The performance of a Pt(II) diazapyrenium-based metallacycle as a reusable substoichiometric catalyst for the SNAr reaction between halodinitrobenzenes and sodium azide at rt in aqueous media is reported. The results suggest that the catalytic effect is promoted by the association of the azide to the diazapyrenium cationic subunits of the catalyst. The findings demonstrate that the formation of an inclusion complex between pyrene and the metallacycle has a regulatory effect over the system, resulting in allosteric-like inhibition of the SNAr reaction.

Metallacycle

Sodium azide

Cationic polymerization

10.1021/jo402689p

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Citations (17)

Novel naphthyridine-based compounds in small molecular non-doped OLEDs: synthesis, properties and their versatile applications for organic light-emitting diodes

New Journal of Chemistry (2012)

Antonio Fernández‐Mato José M. Quintela Carlos Peinador

A series of six new n-type conjugated 1,8-naphthyridine oligomers were examined in organic light emitting diodes (OLEDs). The compounds show a high fluorescence in both solution (10−8 M) and the solid state. The naphthyridines have high glass-transition (Tg = 65–105 °C) and decomposition (Td = 380–400 °C) temperatures, reversible electrochemical reduction, and high electron affinities (2.79–3.00 eV). Systematic variation of the spacer linkage can modulate and fine-tune their properties. They emit high blue, green and yellow photoluminescence with 0.70–1.0 quantum yields. Good-performance, single-layer emitter OLEDs with yellow to white-pink emission have also been demonstrated using these materials. White-pink emitter give a performance with a high brightness (400 cd m−2 at 4 V), and 0.6 cd A−1. Yellow emitters give the best performance with maximum brightness of 250 cd m−2 with a maximum current efficiency of 1.2 cd A−1. These results demonstrate the potential of this new class of n-type conjugated oligomers as emitters and electron-transport materials for developing high-performance yellow to white-pink OLEDs.

Quantum Efficiency

10.1039/c2nj40279c

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Citations (19)