This paper discussed the application of reinforced thermoplastic pipes in oilfields in China. The properties, qualification tests and standard systems for flexible pipes were also reviewed. Finally, problems met during service were analyzed and some suggestions for future application of reinforced thermoplastic pipes were given.
Nano-ZnO particles were deposited on the surface of silver nanowires (AgNWs) by the precipitation method, and the obtained AgNW@ZnO filler with core-shell structure was added to epoxy resin to prepare AgNW@ZnO/EP thermally conductive composites. The ZnO coating on the surface of AgNWs effectively improves the thermal conductivity of the composites. When 8 wt% AgNW@ZnO filler was added to the epoxy resin, the thermal conductivity of the AgNW@ZnO/EP composite increased to 0.77 W/(m·K). The enhancement of the thermal conductivity is attributed to the fact that ZnO effectively improves the interface bonding between AgNWs and the epoxy matrix, thus strengthening the contact between AgNWs. In addition, the electrical insulation of the AgNW@ZnO/EP composites was improved upon the introduction of the ZnO coating over AgNWs. For the filler content of 8 wt%, the volume resistivity of the AgNW@ZnO/EP composites was found to be higher than 10
This research aimed to provide an understanding of the selection and safe application of pipeline liner materials for hydrogen transport by examining the permeation properties and mechanisms of hydrogen within polymers commonly used for this purpose, such as high-density polyethylene (HDPE) and ethylene-vinyl alcohol copolymer (EVOH), through molecular simulation. The study was carried out within defined operational parameters of temperature (ranging from room temperature to 80 °C) and pressure (from 2.5 to 10 MPa) that are pertinent to hydrogen pipeline infrastructures. The results reveal that with an increase in temperature from 30 °C to 80 °C, the solubility, diffusion, and permeability coefficients of hydrogen in HDPE increase by 18.7%, 92.9%, and 129.0%, respectively. Similarly, in EVOH, these coefficients experience increments of 15.9%, 81.6%, and 112.7%. Conversely, pressure variations have a negligible effect on permeability in both polymers. HDPE exhibits significantly higher hydrogen permeability compared to EVOH. The unique chain segment configuration of EVOH leads to the formation of robust hydrogen bonds among the hydroxyl groups, thereby impeding the permeation of hydrogen. The process by which hydrogen is adsorbed in polymers involves aggregation at low potential energy levels. During diffusion, the hydrogen molecule primarily vibrates within a limited range, with intermittent occurrences of significant hole-to-hole transitions over larger distances. Hydrogen exhibits a stronger interaction with HDPE compared to EVOH, leading to a higher number of adsorption sites and increased hydrogen adsorption capacity in HDPE. Hydrogen molecules move more actively in HDPE than in EVOH, exhibiting greater hole amplitude and more holes in transition during the diffusion process.
Abstract To determine the permeability properties of lining materials for the design of nonmetallic pipes in oil and gas fields, we conducted a study on the transport behavior of pure and mixed gases (carbon dioxide [CO2] / methane [CH4]) through commonly used thermoplastic-lined pipe materials. The material tested were high-density polyethylene (HDPE), polyamide (PA), and polyvinylidene fluoride (PVDF). It was observed that the permeability coefficient of the pure gas through HDPE, PA12, and PVDF increased with increasing temperature. The permeation of mixed gas with different volume fractions was also tested at different temperatures, in which the deviation between the test and the ideal state was founded. For HDPE and PVDF, the permeability coefficient of the mixed gas is higher than that of pure gas because of the plasticization effect of CO2. However, for PA12, the permeability coefficient of mixed gas is lower than that of the pure gas. This is because of the tight interaction between the chains and the competition between CO2 and CH4 for a limited number of active sites.
Multicomponent boron-containing carbide coating (i.e., (Zr,Ti)CxBy) on a C/C composite shows good ablation resistance. However, the high temperature oxidation behavior of this new type of boron-containing (Zr,Ti)CxBy solid solution ceramic has not been clarified yet. The present work fabricated (Zr,Ti)CxBy solid solution block ceramic by spark plasma sintering and its oxidation behavior at 1600°C in air (N2–20-vol.% O2) was investigated for the first time. The effects of boron on the oxidation resistance of (Zr,Ti)CxBy ceramic were examined. The results indicate that (Zr,Ti)CxBy ceramic displays a good oxidation resistance with a parabolic rate law described oxidation process. After trace solution of boron (0.5 wt%) into (Zr,Ti)Cx, the oxidation resistance of carbide ceramic is significantly enhanced, leading to a decrease of 30% of oxidation rate constant. The formed oxide scale in (Zr,Ti)CxBy ceramic is dense and the interlayer shows a stronger ability of inhibiting the inward diffusion of oxygen. In addition, the introduction of boron leads to a more negative binding energy of (Zr,Ti)CxBy and improves the oxidation resistance of carbide.
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