В.В. Шарутин

An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures.

10.5517/ccdc.csd.cc29zzny

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Russian Journal of Coordination Chemistry (2003)

В.В. Шарутин И.В. Егорова T.K. Ivanenko А.В. Герасименко

Bismuth

10.1023/a:1022854727489

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Synthesis and structure of tris(4-fluorophenylantimony) dicarboxylates: (4-FC6H4)3Sb[OC(O)R]2, R = CH2I, C6F5

Russian Chemical Bulletin (2017)

В.В. Шарутин О.К. Шарутина

Iodoacetic acid

10.1007/s11172-017-1796-6

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Synthesis and structure of tetra- and triphenylantimony salicylaldoximates

Russian Journal of Inorganic Chemistry (2012)

В.В. Шарутин О.К. Шарутина O.V. Molokova

Tetra

10.1134/s0036023612010226

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(4-Fluorobenzyl)triphenylphosphonium Hexachlorozirconate [Ph3PCH2C6H4F-4][ZrCl6]: Synthesis and Structure

Russian Journal of Coordination Chemistry (2023)

В.В. Шарутин О.К. Шарутина А. В. Рыбакова Oleg S. Eltsov

Fluorine

10.1134/s1070328423700380

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The synthesis methods of phosphorus compounds R4PX, where X is an electronegative group

Bulletin of the South Ural State University series Chemistry (2024)

В.В. Шарутин E. S. Mekhanoshina M. Sakhautdinova D. Baygildina M. Morodetskikh

Based on the analysis of literature sources from the beginning of the 21st century to the present, various methods for obtaining phosphorus compounds of the general formula R4PX (X is an electronegative group) have been systematized and described. The present study is a continuation of classical research in the field of chemistry of organic phosphorus compounds in the Laboratory of Chemistry of Organoelement Compounds of South Ural State University. The prin-cipal attention is paid to synthesis methods for tetraorganylphosphonium derivatives based on radical redistribution reactions and substitution reactions, which are used to synthesize tetra-phenylphosphorus bromide and a series of alkyltriphenylphosphonium arenesulfonates, respec-tively. It has been shown that the single product of the interaction of triphenylphosphorus dibro-mide with pentaphenylphosphorus in a benzene solution (1 hour, 25 °C) is tetraphenylphosphoni-um bromide, isolated from the reaction mixture, yielding 92%. Tetraphenylphosphonium benzene-sulfonate has been obtained, yielding 90%, by a substitution reaction from tetraphenylphosphoni-um bromide and benzenesulfonic acid in water. Using a similar scheme, a series of alkyltri-phenylphosphonium arenesulfonates have been obtained with yields up to 92 %: [Ph3PC3H5-cyclo][OSO2Naft-1] (2), [Ph3PCH2СN][OSO2Mez)] (3), [Ph3PCH2СN][OSO2C6H3Сl2-2,5] ∙ ½MeOH (4), [Ph3PCH2OH][OSO2C6H3Сl2-2,5] ∙ H2O (5), [Ph3PEt][OSO2C6H3(NO2)2-2,4] (6), [Ph3P(СH2)2OH] [OSO2C6H3(NO2)2-2,4] (7), [Ph3P(С6H11-cyclo)] [OSO2C6H3(NO2)2-2,4] (8). The complex structures have been proved by IR spectroscopy and X-ray diffraction analysis (XRD). According to the XRD data, crystals of complexes 2–5 have ionic structure; they consist of tetraorganylphosphonium and arenesulfonate anions.

10.14529/chem240106

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