ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTDeep-UV lithographic response and quantum efficiency calculations of poly((trimethylsilyl)methyl Methacrylate-(chloromethyl)styrene) copolymersM. J. Jurek, A. E. Novembre, I. P. Heyward, R. Gooden, and E. ReichmanisCite this: Chem. Mater. 1989, 1, 5, 509–514Publication Date (Print):September 1, 1989Publication History Published online1 May 2002Published inissue 1 September 1989https://pubs.acs.org/doi/10.1021/cm00005a009https://doi.org/10.1021/cm00005a009research-articleACS PublicationsRequest reuse permissionsArticle Views51Altmetric-Citations-LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InRedditEmail Other access optionsGet e-Alertsclose Get e-Alerts
The thermal stabilities of several UV-cured acrylate coatings were examined and it was determined that these materials can undergo oxidative reactions at moderate temperatures (140°C or greater). If these materials are to be exposed to elevated temperatures, thermal stabilizers will be necessary to impart good long-term stability. A number of phenolic antioxidants and hindered amine light stabilizers were evaluated in an epoxy diacrylate coating, and three major factors were found to influence their efficiency. The stabilizers must: 1) be sufficiently soluble in the monomers 2) be stable enough to UV light to survive the cure and 3) have minimal interactions with the photoinitiator. Several stabilizers which meet these criteria have been identified, and thermal analysis data indicate that they can suppress oxidation of the coating. Among these additives, the hindered amine light stabilizers are of particular interest.
