William Blades

Arizona State University

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John R. Scully

University of Virginia

Petra Reinke

University of Virginia

K. Sieradzki

Arizona State University

Debashish Sur

University of Virginia

Mitra L. Taheri

Johns Hopkins University

Elaf Anber

Johns Hopkins University

Arthur C. Reber

Virginia Commonwealth University

Tyrel M. McQueen

Johns Hopkins University

Katie Lutton

University of Virginia

Nathan Smith

Purdue University West Lafayette

Cooperative Institutions

University of Virginia

Johns Hopkins University

McCormick (United States)

Pennsylvania State University

Materials Science & Engineering

National Institute of Standards and Technology

Northwestern University

University of Baltimore

Arizona State University

American Society For Engineering Education

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History of Blanchardin and Eglantine

Cambridge University Press eBooks (2014)

William Blades

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10.1017/cbo9781107446328.089

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The Recuyell of the Histories of Troy

Cambridge University Press eBooks (2014)

William Blades

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10.1017/cbo9781107446328.012

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DUST AND NEGLECT

Cambridge University Press eBooks (2014)

William Blades

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Content (measure theory)

10.1017/cbo9781107711174.004

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High-throughput aqueous passivation behavior of thin-film vs. bulk multi-principal element alloys in sulfuric acid

Corrosion Science (2024)

William Blades Debashish Sur Howie Joress Brian DeCost Emily F. Holcombe

Multi-principal element alloys have the potential to show excellent passivation behavior. However, the detailed compositional and crystal structure design of these alloys requires a high-throughput strategy. We used combinatorial thin-film libraries of single-phase (FeCoNi)1-x-yCrxAly alloys and compared their passivation behaviors to corresponding bulk alloys. Our results demonstrate that the detailed passivation behaviors of thin-films and bulk alloys are different which is related to both nanoscale porosity within the thin-films and grain boundary dissolution. Nevertheless, we found that comparisons made among suitably designed sets of thin-film alloys can be used to determine the best corrosion performing bulk alloy composition.

Passivation

10.1016/j.corsci.2024.112261

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Tuning chemical short-range order for stainless behavior at reduced chromium concentrations in multi-principal element alloys

arXiv (Cornell University) (2024)

William Blades Benjamin W. Y. Redemann Nathan Smith Debashish Sur M. S. Barbieri

Single-phase multi-principal element alloys (MPEAs) hold promise for improved mechanical properties as a result of multiple operative deformation modes. However, the use of many of these alloys in structural applications is limited as a consequence of their poor aqueous corrosion resistance. Here we introduce a new approach for significantly improving the passivation behavior of alloys by tuning the chemical short-range order (CSRO) parameter. We show that the addition of only 0.03 to 0.06 mole fraction of Al to a (FeCoNi)0.9Cr0.1 alloy changed both the magnitude and sign of the Cr-Cr CSRO parameter resulting in passivation behavior similar to 304L stainless steel containing twice the amount of Cr. Our analysis is based on comparing electrochemical measures of the kinetics of passive film formation with CSRO characterizations using time-of-flight neutron scattering, cluster expansion methods, density functional theory and Monte Carlo techniques. Our findings are interpreted within the framework of a recently proposed percolation theory of passivation that examines how selective dissolution of the non-passivating alloy components and CSRO results in excellent passive films at reduced levels of the passivating component.

Short range order

10.48550/arxiv.2403.00086

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Stans Puer ad Mensam

Cambridge University Press eBooks (2014)

William Blades

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10.1017/cbo9781107446328.025

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Ditto ditto 2nd edition

Cambridge University Press eBooks (2014)

William Blades

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10.1017/cbo9781107446328.029

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WILLIAM CAXTON, THE MERCER. A.D. 1423—1471

Cambridge University Press eBooks (2014)

William Blades

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10.1017/cbo9781107446311.002

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Directorium Sacerdotum, 2nd edition

Cambridge University Press eBooks (2014)

William Blades

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10.1017/cbo9781107446328.080

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THE BOOKBINDER

Cambridge University Press eBooks (2014)

William Blades

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10.1017/cbo9781107446328.008

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