Alexander C. Filippou

Cyclooctene

Reactivity

10.1016/j.jorganchem.2013.04.022

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Citations (17)

Metal–Silicon Triple Bonds: Nucleophilic Addition and Redox Reactions of the Silylidyne Complex [Cp(CO)₂MoSi‐R]

Angewandte Chemie International Edition (2010)

Alexander C. Filippou Oleg Chernov Gregor Schnakenburg

As a silicon analogue of metal alkylidyne complexes, the title compound offers new perspectives in organosilicon chemistry. The high synthetic potential of 1 is demonstrated by a series of reactions that provide access to the first anionic silylidene complexes and dianionic silyl complexes (see scheme; Nu= Cl, N3, CH3; R=C6H3-2,6-Trip2).

Organosilicon

Nucleophilic Addition

10.1002/anie.201005794

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Citations (52)

CCDC 118606: Experimental Crystal Structure Determination

The Cambridge Structural Database (1998)

Alexander C. Filippou J. Winter Gabriele Kociok‐Köhn I. Hinz

An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures.

Crystal (programming language)

10.5517/cc3zf0h

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Übergangsmetall-carbin-komplexe

Journal of Organometallic Chemistry (1986)

Alexander C. Filippou Ernst Otto Fischer Helmut G. Alt

Carbyne

Isopropyl

Substitution reaction

10.1016/0022-328x(86)80198-x

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Citations (10)

Mononuclear bis-aminocarbyne complexes of tungsten with Tp′ ligands; theory of metal-centred carbyne-carbyne coupling

Journal of Organometallic Chemistry (1993)

Alexander C. Filippou Peter Hofmann Paul Kiprof Helmut R. Schmid Carola Wagner

Carbyne

Alkyne

Acetylene

Triple bond

Decarbonylation

10.1016/0022-328x(93)86076-t

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Citations (36)

Synthese und Struktur der Germylinkomplexe trans-[X(dppe)2W≡Ge(1-Cp*)] (X=Cl, Br, I) und Vergleich der W≡E-Bindungen (E=C, Ge) mit Dichtefunktionalrechnungen

Angewandte Chemie (2000)

Alexander C. Filippou Athanassios I. Philippopoulos Peter Portius Dirk U. Neumann

Eine kurze W-Ge-Dreifachbindung und einen η1-gebundenen Cp*-Substituenten weisen die durch Umsetzung von 1 mit den Germylenen [Cp*GeX] erhaltenen Germylinkomplexe 2⋅Toluol auf (W-Ge 2.302(1) Å für X=Cl). Wie Dichtefunktionalrechnungen ergaben, bestehen in elektronischer Hinsicht deutliche Unterschiede zwischen Germylin- und Carbinliganden. X=Cl, Br, I; PP=Ph2PCH2CH2PPh2; Cp*=C5Me5.

10.1002/1521-3757(20000804)112:15<2881::aid-ange2881>3.3.co;2-n

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CCDC 924157: Experimental Crystal Structure Determination

The Cambridge Structural Database (2013)

Alexander C. Filippou Yury Lebedev Oleg Chernov Martin Straßmann Gregor Schnakenburg

An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures.

10.5517/cc100nj6

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The Hexaazidosilicate(IV) Ion: Synthesis, Properties, and Molecular Structure.

ChemInform (2003)

Alexander C. Filippou Peter Portius Gregor Schnakenburg

Abstract For Abstract see ChemInform Abstract in Full Text.

10.1002/chin.200302019

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CCDC 149852: Experimental Crystal Structure Determination

The Cambridge Structural Database (2001)

Alexander C. Filippou Peter Portius Christopher K. Jankowski

An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures.

Crystal (programming language)

10.5517/cc50xy0

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CCDC 800705: Experimental Crystal Structure Determination

The Cambridge Structural Database (2011)

Alexander C. Filippou Oleg Chernov Gregor Schnakenburg

An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures.

10.5517/ccvw663

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Alexander C. Filippou

Papers

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H-Index

i-10 index

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H-Index

i-10 index