An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures.
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures.
The isothermal dissolution method was applied for the phase equilibria experiment of the reciprocal quinary system Li+, K+, Rb+//Cl–, Borate-H2O at 323.2 K; the related density (ρ) of the system was measured by the specific gravity bottle method experimentally, and the crystalloid forms of the equilibrated solid phase were identified by the X-ray diffraction method. Results show that the system belongs to a complex type with the formation of solid solution [(K, Rb)Cl]; meanwhile, six single salts, LiCl·H2O, KCl, RbCl, Li2B4O7·3H2O, K2B4O5(OH)4·2H2O, and RbB5O6(OH)4·2H2O, were also formed at 323.2 K; no double salt was found in this system. The space phase diagram consists of five quinary invariant points, fifteen isothermal dissolution curves, and seven crystallization fields. The size of the RbB5O6(OH)4·2H2O crystallization field is the largest among the coexisting salts in the quinary system. Under the condition of RbB5O8 saturation, the crystallization field of Li2B4O7·3H2O occupied the largest crystallization region, and salt RbCl had the smallest region.
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures.
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures.
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures.
A series of isomorphous second-sphere coordination compounds [MII(DABP)3]3[Cr(C2O4)3]2·14H2O (DABP = 5,5′-diamino-2,2′-bipyridine; M = Cu (1), Ni (2), Fe (3), Zn (4), and Mn (5)) have been constructed through multiple charge-assisted N–H‐–O hydrogen-bonding interactions between the oxalate ligands in [Cr(C2O4)3]3– (unit B) and the NH2 groups in the [M(DABP)3]2+ complex (unit A). The chiral [M(DABP)3]2+ cations and [Cr(C2O4)3]3– anions with the same Λ (or Δ) configuration interdigitate alternately, affording linear A3B2 secondary building units. Two adjacent A3B2 units adopting opposite configurations are linked by a six-cornered star-shaped 14-water cluster of S 6 symmetry (unit C) to form a racemic 1D linear chain –A3B2(Λ)–C–A3B2(Δ)–C–. The microstructure of compound 1 shows a 3D flower-like morphology.
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures.
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures.
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures.
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