Alexandre Picot

Université Toulouse III - Paul Sabatier

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Chantal Andraud

École Normale Supérieure de Lyon

Audrey Auffrant

École Polytechnique

Olivier Maury

Centre National de la Recherche Scientifique

Sylviane Sabo‐Etienne

Laboratoire de Chimie de Coordination

Laure Vendier

Laboratoire de Chimie de Coordination

François P. Gabbaı̈

Texas A&M University

Boris Le Guennic

Institut des Sciences Chimiques de Rennes

Floriane Malvolti

Institut des Sciences Chimiques de Rennes

Patrice L. Baldeck

Centre National de la Recherche Scientifique

Pascal Le Floch

École Polytechnique

Cooperative Institutions

Centre National de la Recherche Scientifique

Université Claude Bernard Lyon 1

École Normale Supérieure de Lyon

Laboratoire de Chimie

Université de Rennes

Université Toulouse III - Paul Sabatier

Texas A&M University

Canadian Nautical Research Society

Institut des Sciences Chimiques de Rennes

Max-Planck-Institut für Kohlenforschung

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CCDC 839855: Experimental Crystal Structure Determination

The Cambridge Structural Database (2011)

H. B. Dyer Alexandre Picot Laure Vendier Audrey Auffrant P. Le Floch

An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures.

10.5517/ccx5y33

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Interplay Between Hydrido/Dihydrogen and Amine/Amido Ligands in Ruthenium Catalyzed Transfer Hydrogenation of Ketones (pub)

HAL (Le Centre pour la Communication Scientifique Directe) (2010)

Alexandre Picot H.E. Dyer Antoine Buchard Audrey Auffrant Laure Vendier

Transfer hydrogenation

Noyori asymmetric hydrogenation

Dihydrogen complex

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Interplay between Hydrido/Dihydrogen and Amine/Amido Ligands in Ruthenium-Catalyzed Transfer Hydrogenation of Ketones

Inorganic Chemistry (2010)

Alexandre Picot H.E. Dyer Antoine Buchard Audrey Auffrant Laure Vendier

This work describes the synthesis of three key intermediates of Noyori-type catalytic systems that are active precatalysts for the transfer hydrogenation of acetophenone. Isolation of the cationic chloro(dihydrogen) complex [RuCl(H(2))(H(2)NNPP)(PCy(3))][BArf(4)] provides a facile synthetic route to the corresponding cationic and neutral hydrido complexes, and the series highlights the links between hydride/dihydrogen and amine/amido ligands in neutral and cationic species.

Transfer hydrogenation

Dihydrogen complex

Noyori asymmetric hydrogenation

10.1021/ic902339j

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Citations (21)

Two-Photon Antenna Effect Induced in Octupolar Europium Complexes

Inorganic Chemistry (2007)

Alexandre Picot Floriane Malvolti Boris Le Guennic Patrice L. Baldeck J. A. Gareth Williams

The synthesis of new chromophore-based pyridine-dicarboxamide ligands and related D3 symmetric europium(III) complexes is described. The photophysical properties of the ligands and the complexes were thoroughly investigated and interpreted on the basis of theoretical calculations (TD-DFT). Finally, the luminescence of Eu(III) was sensitized by two-photon absorption of the ligand, illustrating the two-photon antenna effect phenomenon.

Europium

Chromophore

Two-photon excitation microscopy

10.1021/ic062181x

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Citations (102)

ChemInform Abstract: Benzene (toxic effects in humans and their mode of action; preventive measures).

Chemischer Informationsdienst (1986)

Alexandre Picot

Mode (computer interface)

Citation impact

10.1002/chin.198611372